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Selected Publications

Dr. Wim Pyckhout-Hintzen

Publications Dr. W. Pyckhout-Hintzen, FZJ-ICS-1


References


[87] E. Huebner, J. Allgaier, M. Meyer, J. Stellbrink,W. Pyckhout-Hintzen, D. Richter,
”Synthesis of Polymer/Silica Hybrid Nanoparticles Using anionic Polymerization
Techniques” , Macromolecules,43,856-867(2009)
[86] T. Friedrichs, B. Tieke, M. Meyer, W. Pyckhout-Hintzen, V. Pipich,” Thermore-
sponsive Copolymer Hydrogels, based on N-isopropylacrylamide anc Cationic
Surfactant monomers prepared from micellar solution and microemulsion in a
one-step reaction”,J. Phys. Chem.,(2010)
[85] M. Zamponi, W. Pyckhout-Hintzen, A. Wischnewski, M. Monkenbusch, L. Will-
ner, D. Richter, ”Molecular Observation of branch point motion in star polymer
melts”, Macromolecules, 43,518-524(2009)
[84] F. Stadler, W. Pyckhout-Hintzen, C. Bailly ”Linear viscoelastic rheology of
moderately entangled telechelic polybutadiene temporary networks” , Macro-
molecules, 42,6181-6192(2009)
[83] J. Oberdisse,W. Pyckhout-Hintzen, E. Straube ” Structure determination of Poly-
mer Nanocomposites by Small Angle Scattering” in ’Recent Advances in Poly-
mer Nanocomposites’, 397-438, eds. S. Thomas and G. E. Zaikov, and S.V. Val-
saraj, Brills (Leiden, Boston),2009
[82] G. Van der Donk, M. van Schilt, W. Pyckhout-Hintzen, H. Bouwmeester, T. Van
Gestel, N. Benes, W. Meulenberg: ”Development and performance of microp-
orous TiO2-ZrO2 composite membranes (for gas separation)” J. Membrane Sci-
ence, submitted 1st june 2008
[80] T. Zacherle, A. Wischnewski, W. Pyckhout-Hintzen, J. Allgaier, D. Richter,
L. Van Eijck: ”Segmental dynamics of PEO in Montmorillonite” Macro-
molecules,submitted 20th may 2008
[79] F. Stadler, W. Pyckhout-Hintzen, C. Bailly ”Linear and nonlinear rheological
characterization of temporary networks of telechelic polybutadiene” , Conference
proceedings of the 15th International Congress on Rheology/80th Annual Meet-
ing of the Society-of-Rheology, Monterey Source: XVTH INTERNATIONAL
CONGRESS ON RHEOLOGY - THE SOCIETY OF RHEOLOGY 80TH AN-
NUAL MEETING, PTS 1 AND 2 Volume: 1027 Pages: 552-554 (2008)
[78] K. Niedzwiedz, A. Wischnewski, W. Pyckhout-Hintzen, J. Allgaier, D. Richter,
A. Faraone: ”Chain dynamics and viscoelastic properties of poly(ethylene ox-
ide)” Macromolecules, 41,4866-4872(2008)

[77] M. Kapnistos1, M. Lang, D. Vlassopoulos, W. Pyckhout- Hintzen, D. Richter, D.
Cho, T. Chang, J. Roovers, and M. Rubinstein: ”Beyond reptation and retraction:
Power-law relaxation in entangled ring polymers” Nature materials, 7(12),997-
1002(2008)
[76] H.D. Burrows, M. Knaapila, A.P. Monkman, M.J. Tapia, S.M. Fonseca,
M.L. Ramos, W. Pyckhout-Hintzen, S. Pradhan, U.Scherf: ”Structural stud-
ies on cationic poly9,9-bis[N,N,N-trimethylammonium) alkyl]fluorene-co-1,4-
phenyleneiodides in aqueous solutions in the presence of th enoninioic surfactant
pentaethyleneglycol monododecyl ether (C12E5)” J. Phys.: Condens. Matter 20
(2008) 104210
[75] Y.Karatas, W. Pyckhout-Hintzen, R. Zorn, D. Richter, H.D. Wiemhoe-
fer: ”SANS investigation of chain dynamics in pure and salt-containing
poly(bismethoxyphosphazene)” Macromolecules,41,2212-2218(2008)
[74] J. Oberdisse, P. Hine, W. Pyckhout-Hintzen: ”Structure of interacting aggregates
of silica nanoparticles in a polymer matrix: Small-angle scattering and Reverse
Monte-Carlo simulations” Soft Matter, 2, 476 - 485,2007.
[73] H.H. Hermes, H. Frielinghaus, W. Pyckhout-Hintzen, D. Richter: ”Quantitative
analysis of small angle neutron scattering data from montmorillonite dispersions”
Polymer,47,2147-2155,2006
[72] C. Svanberg, W. Pyckhout-Hintzen, L. Boerjesson: ”Network Structure of
Poly(methyl methacrylate)-based Gels and Gel Electrolytes” Electrochimica
Acta,51,4153-4156,2006
[71] A. Botti,W. Pyckhout-Hintzen, D. Richter, V. Urban, E. Straube: ”A microscopic
look at the reinforcement of silica filled rubber” J. Chem. Phys., 1,124,2006
[70] Emanuela Di Cola, Thomas A. Waigh, John Trinick, Larissa Tskhovrebova,
Ahmed Houmeida, Wim Pyckhout-Hintzen, Charles Dewhurst: ”Persistence
length of titin from rabbit skeletal muscles measured with scattering and mi-
crorheology techniques” Biophysical journal, 88(6),4095 (2005)
[69] Edoardo De Luca, Thomas A. Waigh, Joon Seop Kim, Ho Seung Jeon,
Wim Pyckhout-Hintzen: ”Phase separation in randomly charged polystyrene
sulphonate ionomer solutions” Polymer,46,7109-7117(2005)
[68] Y. Dror, W. Salalha, W. Pyckhout-Hintzen, A. Yarin, E. Zussman, Y. Cohen:
”From carbon nanotube dispersion to composite nanofibers” Progress in Colloid
and Polymer Science, 130:64-69(2005)
[67] Y. Dror, W. Pyckhout-Hintzen, Y. Cohen: ”The conformation of polymers dis-
persing single-walled carbon nanotubes in water: a small angle neutron scattering
study” Macromolecules, 38,7828-7836(2005)

[66] G. Kemmerling, U. Clemens, R. Engels, M. Heiderich, W. Pyckhout-Hintzen,
H. Rongen, J. Schelten, D. Schwahn, K. Zwoll: ”Performance measurements
of a new large area neutron scintillation detector” system IEEE Transactions on
Nuclear Science, 51 (2004), 3, 1098 - 1102
[65] G. Kemmerling, U. Clemens, R. Engels, M. Heiderich, W. Pyckhout-Hintzen,
H. Rongen, J. Schelten, D. Schwahn, K. Zwoll, ”Performance measurements of a
new large area neutron scintillation detector system, proceedings of IEEE Nuclear
Science Symposium/Medical Imaging Conference,(2003) Portland, IEEE NU-
CLEAR SCIENCE SYMPOSIUM, CONFERENCE RECORD, VOLS 1-5 Book
Series: IEEE NUCLEAR SCIENCE SYMPOSIUM - CONFERENCE RECORD
Pages: 722-726 (2004)
[64] A. Blanchard, R.S. Graham, M. Heinrich,W. Pyckhout-Hintzen, D. Richter, A.E.
Likhtman, T.C.B. McLeish, D.J. Read, E. Straube, J. Kohlbrecher: ”SANS ob-
servation of chain retraction after a large step deformation” Phys. Rev. Lett, 95,
166001(2005)
[63] A. Arbe, A. Moralm A. Alegria, J. Colmenero, W. Pyckhout-Hintzen, D. Richter,
” Neutron scattering and dielectric study on the structural and dynamical peculiar
properties of poly(vinyl chloride)” Conference Proceedings of 3rd International
Symposium on Slow Dynamics in Complex Systems, (2003) Sendai, JAPAN
Source: SLOW DYNAMICS IN COMPLEX SYSTEMS Volume: 708 Pages:
594-597 (2004)
[62] M. Goad, W. Pyckhout-Hintzen, S. Kahle, J. Allgaier, D. Richter, L.J. Fetters:
”Rheological properties of 1,4-polyisoprene over a large molecular weight range”
Macromolecules,37,8135-8144(2004)
[61] E. Di Cola, N. Plucktaveesak, T.A. Waigh, R.H. Colby, J. Tan, W. Pyckhout-
Hintzen, R. Heenan: ”Structure and dynamics in aqoueous solutions of am-
phiphilic sodium maleate-containing alternating copolymers” Macromolecules,
37,8457-8465(2004)
[60] A. Botti, W. Pyckhout-Hintzen, D. Richter, V. Urban, E. Straube, J. Kohlbrecher:
”Silica filled elastomers: polymer chain and filler characterization in the unde-
formed state by a SANS-SAXS approach” Polymer, 44,7505-7512(2003)
[59] M. Heinrich, W. Pyckhout-Hintzen, J. Allgaier, D. Richter, E. Straube, T.C.B.
McLeish, A. Wiedenmann, R. Blackwell, D. Read: ”Small-Angle Neutron scat-
tering study of the relaxation of a melt of Polybutadiene H-polymers following a
large step strain” Macromolecules, 37,5054-5064 (2004)
[58] P. Lang, L.Willner,W. Pyckhout-Hintzen, R. Krastev: ”Isotropic to nematic tran-
sition in solutions of cylindrical PB-PEO block copolymer micelles close to a
wall” Langmuir,19,7597-7603 (2003)
[57] G. Belina, V. Urban, E. Straube, W. Pyckhout-Hintzen, M. Klueppel, G. Hein-
rich: ”Microscopic deformation of filler particles in rubber under uniaxial defor-
mation” Macromolecular symposia,200,121-128 (2003)

[56] D. Read, T.C.B. McLeish, M. Heinrich, W. Pyckhout-Hintzen, J. Allgaier, D.
Richter: ”Elastic inhomogeneities in branched polymer melts as revealed by neu-
tron scattering” Abstract of ACS,Poly, 226,U388 (2003)
[55] A. Wischnewski, M. Zamponi, M. Monkenbusch, L. Willner, W. Pyckhout-
Hintzen, D. Richter, A. Likhtman. T.C.B. McLeish, B. Farago: ”Molecular
observation of contour length fluctuations in polymer melts”, Physica B DOI
10.1016/j.physb.2004.04.024
[54] C. Kluthe, T. Al-Kassab, J. Barker, W. Pyckhout-Hintzen, R. Kirchheim: ”Segre-
gation of hydrogen at internal Ag/MgO (metal/oxide)-interfaces as observed by
small angle neutron scattering”, Acta Materialia, 52,2701-2710 (2004)
[53] J. Berriot, H. Montes, F. Martin, M. Mauger, W. Pyckhout-Hintzen, G. Meier,
H. Frielinghaus: ”Reinforcement of model filled elastomers: synthesis and char-
acterization of the dispersion state by SANS measurements”, Polymer 44,4909-
4919 (2003)
[52] Prinz, D., Pyckhout-Hintzen, W., Krooss, B., Littke, R.: ”Investigations on the
Micro- and Mesoporous Structure of Coals of Varying Rank: A Combined Small
Angle Neutron and Gas Adsorption Experiments Study”, Proceedings of the Int.
Coalbed Methane Symposium 2001, 419-432, Tuscaloosa, Alabama.
[51] D. Prinz, D, W. Pyckhout-Hintzen, R. Littke,” Development of the meso- and
macroporous structure of coals with rank as analysed with small angle neutron
scattering and adsorption experiments”, FUEL, 83 (4-5) 547-556 (2004)
[50] K.Gohr, W. Schaertl, L. Willner, W. Pyckhout-Hintzen: ”SANS investigatons
of PS-PB block copolymer micelles in a short chain PB homopolymer matrix”
Macromolecules,35,9110-9116,2002
[49] A. Botti, W. Pyckhout-Hintzen, D. Richter, E. Straube: ”An in situ rheological
and SANS investigation of the crosslinking reaction of polyisoprene and dicumyl
peroxide” Acta Rheologica,(2002),41:475-482
[48] A. Botti, W. Pyckhout-Hintzen, D. Richter, E. Straube: ”Filled elastomers:
polymer chain and filler characterization by a SANS-SAXS approach” Physica
A,304(2002), 230-234
[47] D. Caspary, G. Eckold, F. Guethoff, W. Pyckhout-Hintzen: ”Kinetics of decom-
position in ionic solids II: neutron scattering study of the system AgCl-NaCl” J.
Phys.: Condens. Matter, 13(2001),11521-11530
[46] M. Heinrich, W. Pyckhout-Hintzen, D. Richter, E. Straube, D.J. Read, T.C.B
McLeish, D.J. Groves, R.J. Blackwell, A. Wiedenmann: ”Arm Relaxation in de-
formed H-Polymers in elongational Flow by SANS” Macromolecules, 35,6650-
6664(2002)

[45] W. Pyckhout-Hintzen, A. Botti, M. Heinrich, S. Westermann, D. Richter, E.
Straube: ”The length-scale dependence of strain in networks by SANS” Appl.
Phys. A74,368-370(2002)
[44] M. Heinrich,W. Pyckhout-Hintzen, D. Richter, E. Straube, A.Wiedenmann: ”Re-
laxation of entangled model H-shaped polymers: a SANS investigation” Appl.
Phys. A74,380-382(2002)
[43] V. Urban, A. Botti, W. Pyckhout-Hintzen, D. Richter, E. Straube: ”Composites
reinforcement by rods: a SAS study” Appl. Phys. A74,510-512(2002)
[42] A. Botti, W. Pyckhout-Hintzen, V. Urban, J. Kohlbrecher, D. Richter, E. Straube:
”Silica-filled elastomers: polymer chain and filler characterization by a SANS-
SAXS approach” Appl. Phys. A74,513-515(2002)
[41] M. Maxelon, A. Pundt, W. Pyckhout-Hintzen, J. Barker, R. Kirchheim: ”Interac-
tions of hydrogen and deuterium with dislocations in palladium as observed by
small angle neutron scattering” Acta Materialia,49(14):2625-2634,2001
[40] M. Maxelon, A. Pundt, W. Pyckhout-Hintzen, R. Kirchheim: ”Small angle neu-
tron scattering of hydrogen segregation at dislocations on palladium” Scripta Ma-
terialia, 44,817-822(2001)
[39] H. Menge, W. Pyckhout-Hintzen, G. Meier, E. Straube: ”Butadiene rubbers:
Topological constraints and microscopic deformations by mechanical and small
angle neutron scattering investigation” Polymer Bulletin,48,183-190(2002)
[38] A. Moral, A. Arbe, A. Alegria, J. Colmenero, W. Pyckhout-Hintzen, D. Richter,
B. Farago, B. Frick: ”Heterogenous structure of poly(vinylchloride) as the origin
of anomalous dynamical behaviour” J. Chem. Phys.,117 (3),1336-1350(2002)
[37] K. Edelmann, M. Janich, E. Hoinkis,W. Pyckhout-Hintzen, S. Hoering: ”The ag-
gregation behaviour of Poly(ethylene oxide)- Poly(methyl methacrylate) diblock
copolymers in organic solvents” Macromol. Chem. Phys.,202,1638-1644(2001)
[36] R. Erhardt, A. Boeker, H. Zettl, H. Kaya, W. Pyckhout-Hintzen, G. Krausch, V.
Abetz, A. Mueller: ”Superstructures of janus micelles” Abstract ACS 221:56-
PMSE,Part2 april 1(2001)
[35] R. Erhardt, A. Boeker, H. Zettl, H. Kaya, W. Pyckhout-Hintzen, G. Krausch,
V. Abetz, A. Mueller: ”Superstructures of janus micelles” Polymeric Materials:
Science & Engineering, 84,(2001)
[34] R. Erhardt, A. Boeker, H. Zettl, H. Kaya, W. Pyckhout-Hintzen, G. Krausch, V.
Abetz, A. Mueller: ”Janus Micelles” Macromolecules,2001,34,1069-1075
[33] D. Richter, M. Monkenbusch,W. Pyckhout-Hintzen, A. Arbe, J. Colmenero: ”Re-
sponse to ’Comment on ”From Rouse dynamics to local relaxation: a neutron spin
echo study on polyisobutylene melts”’” J. Chem. Phys,113,11396(2000)

[32] W. Pyckhout-Hintzen, A. Botti, M. Heinrich, D. Richter, E. Straube, S. West-
ermann, V. Urban: ”SANS of polymer networks under deformation” Zuoz-
8th.Summerschool 2000 Proc., World Scientific publ. Singapore 2000,117-130
[31] A. Botti, W. Pyckhout-Hintzen, D. Richter, E. Straube, V. Urban, J.
Kohlbrecher: ”Chain Deformation in filled elastomers: a SANS approach” Phys-
ica B,2000,276-278,371-372.
[30] S. Westermann, W. Pyckhout-Hintzen, D. Richter, E. Straube, S. Egelhaaf,
R. May: ”On The length scale dependence of microscopic strain by SANS”
Macromolecules,2001,34,2186-2194
[29] W. Pyckhout-Hintzen, S. Westermann, A. Botti, D. Richter, E Straube: ”Chain
Deformation in unfilled and filled Polymer Networks: a SAS Approach” Noti-
zario Neutroni e Luce di Sincrotone,5,34-40(2000)
[28] M. Dreja, W. Pyckhout-Hintzen, H. Mays, B.Tieke: ”Cationic Gemina surfac-
tant with oligo(oxyethylene) spacer groups and their use in the polymerization of
styrene in ternary microemulsion” Langmuir,1999,15,391-399
[27] S. Westermann, W. Pyckhout-Hintzen, P. Thyagarajan, D. Wosniak, D. Richter,
E. Straube: ”A SANS study on thermal degradation kinetics in Polyisoprene net-
works” Mat. Res. Using cold neutons at pulsed neutron sources, eds. P. Thya-
garajan, F. Trouw, B. Marzec, C-K Loong,World Scientific Publ., Singapore,210-
213(1999)
[26] W. Pyckhout-Hintzen, A. Botti, M. Heinrich, D. Richter, E. Straube , S. Wester-
mann, V. Urban,” SANS of polymer networks under deformation”, Novel Mate-
rials, World Science Press (Singapore), 117-130 (2000)
[25] S. Westermann, M. Kreitschmann, W. Pyckhout-Hintzen, D. Richter, E. Straube,
B. Farago, G. Goerigk: ”Matrix chain deformation in reinforced networks: a
SANS approach” Macromolecules,1999,32,5793-5802
[24] S. Westermann, V. Urban, W. Pyckhout-Hintzen, D. Richter, E. Straube: ”Com-
ment on ”Lozenge contour plots in scattering from polymer networks”” Physical
Review Letters,1998,80,5449
[23] M. Dreja, W. Pyckhout-Hintzen, B. Tieke: ”Copolymerization behaviour and
structure of styrene and polymerizable surfactants in three-component cationic
microemulsion” Macromolecules,1998,31,272
[22] W. Pyckhout-Hintzen, S. Westermann, V. Urban, D. Richter, E. Straube: ”SANS
investigations of topological constraints and microscopic deformation in polymer
networks” Physica B,1997,234-236,236-239
[21] S. Westermann, M. Kreitschmann, W. Pyckhout-Hintzen, D. Richter, E. Straube:
”Strain amplification effects in polymer networks” Physica B,1997,234-236,306-
307

[20] S. Westermann, V. Urban, W. Pyckhout-Hintzen, D. Richter, E. Straube: ”SANS
investigations of topological constraints in networks made from triblockcopoly-
mers” Macromolecules,1996,29,6165
[19] E. Straube, V. Urban, W. Pyckhout-Hintzen, D. Richter, C. Glinka: ”Small angle
neutron scattering investigation of topological constraints and tube deformation
in networks” Physical Review Letters,1995,74,4464
[18] E. Straube, V. Urban, W. Pyckhout-Hintzen, D. Richter: ”SANS investigations of
topological constraints and microscopic deformations in rubberelastic networks”
Macromolecules,1994,27,7681
[17] W. Pyckhout-Hintzen, B. Mueller, T. Springer: ”Elastic properties of random-
linked cis-PB networks: a characterization and gel point study” Journal of Ap-
plied Polymer Science,1993,48,887
[16] W. Pyckhout-Hintzen, B. Mueller, T. Springer: ”Characterization and gelpoint
of randomly linked high cis- polybutadiene networks” Makromol. Chem. Macro-
mol. Symp,1993,76,121
[15] A. Zirkel, D. Richter,W. Pyckhout-Hintzen, L. Fetters: ”Temperature dependence
of the unperturbed dimensions of alternating poly(ethylene-propylene)” Macro-
molecules,1992,25,954
[14] R. Butera, L. Fetters, J. Huang, D. Richter, W. Pyckhout-Hintzen, A. Zirkel,
B. Farago, B. Ewen: ”Microscopic and macroscopic evaluation of fundamental
facets of the entanglement concept” Phys. Rev. Letters,1991,66,2088
[13] W. Pyckhout-Hintzen, T. Springer, F. Forster,W. Gronski, C. Frischkorn: ”Small-
angle neutron scattering investigation of a multilinked polybutadiene network
cross-linked in solution” Macromolecules,1991,24,269
[12] W. Gronski, F. Forster,W. Pyckhout-Hintzen, T. Springer: ”Local orientation and
global deformation of network chains in strained elastomeric networks” Springer
Proceedings in Physics,”Molecular basis of polymer networks” Heidelberg,1989
[11] W. Gronski, F. Forster,W. Pyckhout-Hintzen, T. Springer: ”Local orientation and
global deformation of network chains in strained elastomeric networks” Makro-
mol. Chem. Macromol. Symp,1990,40,121
[10] W. Pyckhout-Hintzen, D. Schwahn, I. Sosnowska, T. Springer, H. Yee-Madeira:
”SANS investigations of critical phenomena and phase separations: two examples
of blends with high and low molecular weights” Physica B,1989,156-157,402
[9] N.L. Allinger, H.J. Geise, W. Pyckhout, L.A. Paquette, J.C. Gallucci: ”Structure
of nornorbane and dodecahedrane by molecular mechanics calculations (MM3),
Xray crystallography and electron diffraction” J. Am. Chem. Soc.,111,1106-
1114(1989)

[8] W. Pyckhout, N. Horemnans, C. Van Alsenoy, H.J. Geise, D. Rankin: ”The
molecular structure of pyridine in the gas phase determined from electron diffrac-
tion, infrared and ab initio force field calculations” J. Mol. Struct.,156,315-
329(1987)
[7] W. Pyckhout, I. Callaerts, C. Van Alsenoy, H.J. Geise, A. Almenningen, R. Seip:
”The molecular structure of s-triazine in the gas phase determined from elec-
tron diffraction, infrared/raman and ab initio force field calculations” J. Mol.
Struct.,147,321-329(1986)
[6] W. Pyckhout, C. Van Alsenoy, H.J. Geise, B. Van der Veken, P. Coppens, M.
Traetteberg: ”Vinyl formate in the gasphase investigated by electron diffraction,
microwave spectroscopy and infrared band contour analysis, supplemented with
molecular mechanics and ab initio calculations of geometries and force fields” J.
Mol. Struct.,147,85-104(1986)
[5] W. Pyckhout, C. Van Alsenoy, H.J. Geise: ”Structure of gaseous methyl acetate
as determined by joint analysis of electron diffraction, microwave and infrared
spectroscopy, supplemented by a valence force field and constraibts from geome-
try relaxed ab initio calculations” J. Mol. Struct.,144,265-279(1986)
[4] F. Vanhouteghem, W. Pyckhout, C. Van Alsenoy, L. Van den Enden, H.J. Geise:
”The molecular structure of gaseous allyl alcohol determined from electron
diffraction, microwave, infrared and geometry-relaxed ab initiop data” J. Mol.
Struct.,140,33-48(1986)
[3] W. Pyckhout, C. Van Alsenoy, H.J. Geise, B. Van der Veken, G. Pieters: ”Ro-
tational isomerism in divinyl ether studied by gas phase electron diffraction, mi-
crowave spectroscopy, infrared band profile simulation and ab initio calculations”
J. Mol. Struct.,130,335-353(1985)
[2] W. Pyckhout, H.J. Geise: ”Molecular Orbital Constrained Electron Diffraction”
in: Stereochemical applications of gas-phase electron diffraction ed. by Istvan
Hargittai and Magdolna Hargittai. Part A: The electron diffraction technique -
Weinheim: VCH Verlagsgesellschaft, 1988
[1] W. Pyckhout, P. Van Nuffel, C. Van Alsenoy, L. Van den Enden, H.J. Geise: ”The
molecular structure of gaseous methyl vinyl ether at room temperature, studied by
molecuilar orbital constrained electron diffraction and microwave spectroscopy”
J. Mol. Struct.,102,333-345(1983)


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