La0.6Sr0.4CoO3−δ Films Under Deoxygenation: Magnetic And Electronic Transitions Are Apart from The Structural Phase Transition

Functional oxides, such as La0.6Sr0.4CoO3−δ, are extremely sensitive to their oxygen stoichiometry and can ultimately undergo electronic, magnetic, and structural phase transition with a varying oxygen content. In this study, we relate the magnetic and electronic phase transition occurring in epitaxial La0.6Sr0.4CoO3−δ thin films to the initial loss of oxygen already at an early stage of the reduction process. The structural transition to a phase-pure Brownmillerite phase is subsequently achieved by continuous reduction, resulting in a coherently-ordered final structural phase.

La0.6Sr0.4CoO3−δ Films Under Deoxygenation: Magnetic And Electronic Transitions Are Apart from The Structural Phase Transition

Suqin HeOleg PetracicValeria LauterLei Cao, Yunxia Zhou, Moritz Lukas WeberJürgen SchubertOmar ConcepciónRegina DittmannRainer WaserThomas BrückelFelix Gunkel

Advanced Func. Mater. 34, 24 , 2313208 (07 February 2024) https://doi.org/10.1002/adfm.202313208

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Dr. Felix Gunkel

Senior Researcher / Group leader Associate Professor, University of Twente (IMS)

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Prof. Dr. Regina Dittmann

Director Electronic Materials (PGI-7)

  • Peter Grünberg Institute (PGI)
  • Electronic Materials (PGI-7)
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Last Modified: 10.04.2025